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The CALIBRANT Command
The CALIBRANT button allows the fitting of the powder pattern from
a standard calibrant sample. The known D-spacings of the diffracting planes
allow the beam centre and tilt to be defined with greater accuracy
than with an unknown sample, and if reasonably high angle data is
present allow the sample to detector distance, and the wavelength to
be refined independently. This has been verified to agree to within
the accuracy that may be obtained from scanning an absorption edge using a Ge
detector on ID-30 at the ESRF.
Clearly for best results a very high quality powder sample should be
used, and a well exposed image should be obtained.
First the SELECT CALIBRATION SAMPLE choice menu appears. This is
shown in Figure 38.
Figure 38:
The SELECT CALIBRATION SAMPLE Choice Menu
|
The following commands and choice of calibrants is available, and includes the
commonly used samples from the American National Institute of
Standards and Technology:
- CANCEL: Cancel CALIBRANT command and return to
POWDER DIFFRACTION interface menu.
- ALUMINA (Al2O3: Alumina powder sample
- CERIUM DIOXIDE: Ceria powder sample e.g. NIST standard
- ?: Outputs list of choices and short explanation of each choice.
- LANTHANUM HEXABORIDE: powder sample e.g. NIST standard
- PARAFFIN WAX: Macromolecular crystallographers ``standard''
calibration wax. PARAFFIN WAX is included since many crystallographers
use this for distance calibration. However don't expect high accuracy,
and if only low angle data is available don't try to
refine both wavelength and distance together.
- HELP: Outputs help text explaining in greater detail the command
and available choices.
- SODIUM CHLORIDE: NaCl Common salt
(beware of moisture)
- SILICON: Silicon powder sample e.g. NIST standard
- USER DEFINED:
Allows an arbitary series of D-spacings to be input
from a text file. The file must contain only one D-spacing value in Angstroms
per line. This allows for calibration samples which are not in the available
choices, but also allows non-standard D-spacings to be used e.g. for samples at
non-standard temperatures, or allows certain D-spacings to be delibrately
missed, owing to problems of contamination etc. Mixed samples may also be
treated this way.
After the appropriate calibrant sample has been selected, the
CALIBRANT PATTERN REFINEMENT control form appears. This is
shown in Figure 39.
Figure 39:
The CALIBRANT PATTERN REFINEMENT Control Form
|
The following "buttons" are available:
- DISTANCE: The sample to detector distance in millimetres.
- WAVELENGTH: The radiation wavelength in Ångstroms.
- X-PIXEL SIZE: The horizontal (as displayed) size of detector
pixels in microns.
- Y-PIXEL SIZE: The vertical (as displayed) size of detector
pixels in microns.
- ANGULAR SECTIONS: This the number of angular
sections around 360 degrees of the powder rings
which are used to calculate the centre of the
rings. The beam centre and tilt are fitted to
these positions on each ring. If the data is
very noisy or shows poor powder averaging then
a smaller number may be better. (No theoretical
criterion exists to set an optimum value, so
trail and error is recommended. Clearly, this
value should not be too small.)
- REJECT OUTLIERS: This option allows badly
fitting ``ring'' positions to be rejected, and
the data re-fitted. This is to make the fit
procedure more robust and to allow for
erroneous positions owing to contaminating
Bragg peaks, etc.
- REJECT LIMIT: If REJECT OUTLIERS is YES
then this is the number of standard deviations
away from the best fit predicted position after
which ``outliers'' are rejected.
- FULL INFO: YES for terminal screen output of
information relating every stage of the fitting
of the powder rings.
- REFINE BEAM X/Y: YES to fit the beam centre
position, as well as the tilt angles. NO to
refine only the tilt angles (if variable). This
is usually used when the beam centre has been
determined from a direct beam mark.
- REFINE DISTANCE: YES to refine the sample to detector
distance, from the angles of the calibrant powder rings.
- REFINE WAVELENGTH: YES to refine the radiation wavelength
from the angles of the calibrant powder rings.
- REFINE TILT: YES to fit the detector
non-orthogonality to the beam (the tilt).
- EXTRA ITERATIONS: Sometimes the initial values are not good
enough to find higher angle rings. If YES an extra step is
introduced which finds intermediate angle rings and refines using them,
prior to trying to use all available rings. This should normally not be
necessary.
As can be seen it is possible to refine, or not, all the different
parameters. It is possible to refine all parameters together, but
normally only the sample to detector distance or the wavelength should
be refined. However, with high quality, high angle data is possible to refine
both together, and get results as good as those obtained by scanning edges.
Set the required parameters and click O.K. to continue.
The user is prompted to define a ring of the calibrant pattern, by
clicking on the ring 3 or more times. Normally the inner ring is
requested. This defines the inner ring, and an initial beam centre.
This should be last user intervention, provided the initialisation is
not too inaccurate. If the position of the ring does not correspond
within 10% of the given distance and wavelength, then a WARNING
message will be output and the operation will terminate. In such a
case check the initial values and change as required.
When the initialisation is good enough, the routine will successively
search for more ring positions and refine the refinable parameters as
requested. The coordinates use and the rings predicted are drawn on the
image as the command proceeds.
(See Section 11.2.1, Page
for the definition of the tilt angles.)
Next: The CAKE Command
Up: The POWDER DIFFRACTION (2-D)
Previous: The BEAM CENTRE Command
Andrew Hammersley
2004-01-09