23 - Vanadium (V)
Vanadium Datas in eV | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
EK | ΔEK | EL1 | ΔEL1 | EL2 | ΔEL2 | EL3 | ΔEL3 | EKα1 | ΔEKα1 | EKα2 | ΔEKα2 | EKß1 |
5465 | 1.01 | 626.7 | 2.41 | 519.8 | 0.26 | 512.1 | 0.24 | 4952.2 | 1.26a / 1.75b | 4944.64 | 1.28a / 2.38b | 5427.29 |
Main beamline parameters at K-edge | |||||
---|---|---|---|---|---|
Bending Magnet | Monochromator | Mirrors | |||
Vertical div. (mrad) | Cristal type | Angle (°) | Resolution (eV) | Angle (mrad) | Cut-off energy (keV) |
0.240 | Si(220) | 36.26 | 0.280 | 7.1 | 8.2 |
Si(111) | 21.24 | 0.747 |
Main crystal analyzer spectrometer parameters at K-edge | |||
---|---|---|---|
Line | Crystal | ||
Name | E (eV) | Type | Bragg angle (°) |
EKα1 | 4952.2 | Ge(331) | 74.70 |
EKß1 | 5427.29 | Ge(422) | 81.562 |
Si(331) | 66.463 |
Experiments already done with this element / available references
Earth & Environmental Sciences
El Beze L., Rose J., Mouillet V., Farcas F., Masion A., Chaurand P., Bottero J.-Y., “Location and evolution of the speciation of vanadium in bitumen and model of reclaimed bituminous mixes during ageing: Can vanadium serve as a tracer of the aged and fresh parts of the reclaimed asphalt pavement mixture?”, Fuel 102 (2012) 423-430
Chaurand P., Rose J., Briois V., Salome M., Proux O., Nassif V., Olivi L., Susini J., Hazemann J.-L., Domas J., Chateau L., Bottero J.-Y., “Comparison between Vanadium K-edge XANES interpretation methods to determine oxidation state and coordination number”, Journal of Physical Chemistry B 110 (2007) 5101-5110
Chaurand P., Rose J., Briois V., Olivi L., Hazemann J.-L., Proux O., Domas J., Bottero J.-Y., “Environmental impacts of steel slag reused in road construction: a crystallographic and molecular (XANES) approach”, Journal of Hazardous Materials 139 (2007) 537–542
Chaurand Perrine, “Apport de la cristallochimie et de la spéciation du chrome et du vanadium à la modélisation de l’altération de granulats artificiels (sous-produits d’acierie)”, Thèse de l'Université Paul Cézanne (2006)
Material Science
Rodolakis F., Rueff J.-P., Sikora M., Alliot I., Itié J.-P., Baudelet F., Ravy S., Wzietek P., Hansmann P., Toschi A., Haverkort M.W., Sangiovanni G., Held K., Metcalf P. and Marsi M., “Evolution of the electronic structure of a Mott system across its phase diagram: X-ray absorption spectroscopy study of (V1−xCrx)2O3”, Physical Review B 84 (2011) 245113
Rodolakis F., Hansmann P., Rueff J.-P., Toschi A., Haverkort M.W., Sangiovanni G., Saha-Dasgupta T., Held K., Sikora M., Alliot I., Itié J.-P., Baudelet F., Wzietek P., Metcalf P., Marsi M., "Inequivalent routes through the Mott transition in V2O3 explored by x-ray absorption spectroscopy: pressure vs. temperature and doping", Physical Review Letters 104 (2010) 047401
Rodolakis Fanny, “Spectroscopies à l’aide du rayonnement synchrotron appliquées aux systèmes fortement corrélés : Transition métal-isolant dans les oxydes de vanadium”, Thèse de doctorat de l’Université Paris Sud, spécialité Physique (2009)
Liscio F., Maret M., Meneghini C., Hazemann J.-L., Albrecht M., “Properties of ultra thin vanadium layers in V/Ru superlattices”, J. Phys.: Condens. Mat. 19 (2007) 486005
Sadoc A., Heckmann O., Nassif V., Proux O., Hazemann J.-L., Xing L.Q., Kelton K.F., “Local order and nanostructure induced by microalloying in Al-Y-Fe amorphous alloy”, Journal of Non-Crystalline solids 353 (2007) 2758-2766
Chemistry, Catalysis & Electrochemistry
Murayama H., Vitry D., Ueda W., Fuchs G., Anne M., Dubois J.L., “Structure characterization of orthorhombic phase in MoVTeNbO catalyst by powder X-ray diffraction and XANES”, Applied Catalysis A: General 318 (2007) 137-142