26 - Iron (Fe)
Iron Datas in eV | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
EK | ΔEK | EL1 | ΔEL1 | EL2 | ΔEL2 | EL3 | ΔEL3 | EKα1 | ΔEKα1 | EKα2 | ΔEKα2 | EKß1 |
7112 | 1.25 | 844.6 | 2.76 | 719.9 | 0.37 | 706.8 | 0.36 | 6403.84 | 1.61a / 2.46b | 6390.84 | 1.62a / 3.20b | 7057.98 |
Main beamline parameters at K-edge | |||||
---|---|---|---|---|---|
Bending Magnet | Monochromator | Mirrors | |||
Vertical div. (mrad) | Cristal type | Angle (°) | Resolution (eV) | Angle (mrad) | Cut-off energy (keV) |
0.210 | Si(220) | 27.03 | 0.365 | 5.5 | 10.7 (1.5xEK) |
Si(111) | 16.16 | 0.973 |
Main crystal analyzer spectrometer parameters at K-edge | |||
---|---|---|---|
Line | Crystal | ||
Name | E (eV) | Type | Bragg angle (°) |
EKα1 | 6403.84 | Ge(440) | 75.471 |
EKß1 | 7057.98 |
Si(440) Ge(620) |
66.19 79.09 |
Experiments already done with this element / available references
Earth & Environmental Sciences
Dauphas N., Roskosz M., Alp E.E., Neuville D.R., Hu M.Y., Sio C.K., Tissot F.L.H., Zhao J., Tissandier L., Médard E.,Cordier C., “Magma redox and structural controls on iron isotope variations in Earth’s mantle and crust”, Earth and Planetary Science Letters 398 (2014) 127-140
Cochain B., Pinet O., Richet P., “Diffusion of sodium ions driven by charge compensation as the rate-limiting step of internal redox reactions”, Journal of Non-Crystalline Solids 365 (2013) 23-26
Cochain B., Neuville D.R., de Ligny D., Malki M., Testemale D., Pinet O., Richet P., “Dynamics of iron-bearing borosilicate melts: Effects of melt structure and composition on viscosity, electrical conductivity and kinetics of redox reactions”, Journal of Non-Crystalline Solids 373-374 (2013) 18-27
Gonçalves Ferreira P., de Ligny D., Lazzari O., Jean A., Cintora Gonzalez O., Neuville D.R., “Photoreduction of iron by a synchrotron X-ray beam in low iron content soda-lime silicate glasses”, Chemical Geology 346 (2013) 106-112
Picard A., Testemale D., Hazemann J.-L. Daniel I., “The influence of high hydrostatic pressure on bacterial dissimilatory iron reduction”, Geochimica Cosmochimica Acta 88 (2012) 120-129
Daval D., Testemale D., Recham N., Tarascon J.-M., Siebert J., Martinez I., Guyot F., “Fayalite (Fe2SiO4) dissolution kinetics determined by X-ray absorption spectroscopy”, Chemical Geology 275 (2010) 161-175
Testemale D., Dufaud F., Martinez I., Bénezeth P., Hazemann J.-L., Schott J., F. Guyot, “An X-ray absorption study of the dissolution of siderite at 300 bar between 50°C and 100°C”, Chemical Geology 259 (2009) 8-16
Testemale D., Brugger J., Liu W., Etschmann B., Hazemann J.-L., “An XAS study of the chloride complexing of Fe(II) in brines to supercritical conditions”, Chemical Geology 264 (2009) 295-310
Lahlah J., Renault P., Cazevieille P., Buzet A., Hazemann J.-L., Womes M., Cambier P., “Geochemical resilience of a Ferralsol subjected to anoxia and organic matter amendment”, Soil Sci. Soc. Am. J. 73 (2009) 1958-1971
Magnien V., Neuville D.R., Cormier L., Roux J., Hazemann J.-L., de Ligny D., Pascarelli S., Vickridge I., Pinet O., Richet P., “Redox kinetics diffusion mechanisms in silicate melts: the effect of alkali”, Geochimica Cosmochimica Acta 72 (2008) 2157-2168
Material Science
Monnier J., Réguer S., Foy E., Testemale D., Mirambet F., Saheb M., Dillmann P., Guillot I., “XAS and XRD in situ characterisation of reduction and reoxidation processes of iron corrosion products involved in atmospheric corrosion”, Corrosion Science 78 (2014) 293-303
Hillion A., Cavallin A., Vlaic S., Tamion A., Tournus F., Khadra G., Dreiser J., Piamonteze C., Nolting F., Rusponi S., Sato K., Konno T. J., Proux O., Dupuis V., Brune H., “Low Temperature Ferromagnetism in Chemically Ordered FeRh Nanocrystals”, Physical Review Letters 110 (2013) 087207
Bali R., Soares M. M., Ramos A. Y., Tolentino H.C.N., Yildiz F., Boudot C., Proux O., De Santis M., Przybylski M., Kirschner J., “Magnetic and structural properties of the Fe layers in CoO/Fe/Ag(001) heterostructure”, Applied Physics Letters 100 (2012) 132403
Iadecola A., Joseph B., Puri A., Simonelli L., Mizuguchi Y., Testemale D., Proux O., Hazemann J.-L., Takano Y., Saini N. L., “Random alloy-like local structure of Fe(Se,S)1−xTex superconductors revealed by extended X-ray absorption fine structure”, Journal of Physics: Condensed Matter 23 (2011) 425701
Soares M. M., Tolentino H. C. N., De Santis M., Ramos A. Y., Cezar J. C., “Highly anisotropic epitaxial L10 FePt on Pt(001)”, Journal of Applied Physics 109 (2011) 07D725
Iadecola A., Joseph B., Simonelli L., Mizuguchi Y., Takano Y., Saini N. L., “Determination of the local structure in FeSe0.25Te0.75 single crystal by polarized EXAFS”, Europhysics Letters 90 (2010) 67008
Mirambet F., Reguer S., Rocca E., Hollner S., Testemale D., “A complementary set of electrochemical and X-ray synchrotron techniques to determine the passivation mechanism of iron treated in a new corrosion inhibitor solution specifically developed for the preservation of metallic artefacts”, Applied Physics A: Materials Science & Processing (2010)
Chemistry, Catalysis & Electrochemistry
Jeanson A., Berthon C., Coantic S., Den Auwer C., Floquet N., Funke H., Guillaneux D., Hennig C., Martinez J., Moisy Ph., Petit S., Proux O., Quemeneur E., Solari P. L., Subra G., “The role of aspartyl-rich pentapeptides in comparative complexation of actinide(IV) and iron(III). Part 1”, New J. Chem. 33 (2009) 976–985
Biology
Cutruzzola F., Arcovito A., Giardina G., della Longa S., D’Angelo P., Rinaldo S., “Distal–proximal crosstalk in the heme binding pocket of the NO sensor DNR”, Biometals 27 (2014) 763-773
Klein S., Sommer A., Distel L., Hazemann J.-L., Kroener W., Neuhuber W., Muller P., Proux O., Kryschi C., “Superparamagnetic Iron Oxide Nanoparticles as Novel X-ray Enhancer for Low-dose Radiation Therapy”, Journal of Physical Chemistry B 118 (2014) 6159–6166
Arcovito A., Bonamore A., Hazemann J.-L., Boffi A., D'Angelo P. “Unusual proximal heme pocket geometry in the deoxygenated Thermobifida fusca: A combined spectroscopic investigation”, Biophysical Chemistry 147 (2010) 1-7
Arcovito A., Ardiccioni C., Cianci M., D’Angelo P., Vallone B., Della Longa S. “Polarized X-ray Absorption Near Edge Structure spectroscopy of Neuroglobin and Myoglobin Single Crystals”, Journal of Physical Chemistry B 114 (2010) 13223–13231
D’Angelo P., Zitolo A., Pacello F., Mancini G., Proux O., Hazemann J.-L., Desideri A. and Battistoni A. “Fe-heme structure in Cu,Zn superoxide dismutase from Haemophilus ducreyi by X-ray Absorption Spectroscopy”, Archives of Biochemistry and Biophysics 498 (2010) 43–49
D’Angelo P., Della Longa S., Arcovito A., Anselmi M., Di Nola A., Chillemi G. , Desideri A. and Battistoni A. “Dynamic Investigation of Protein Metal Active Sites: Interplay of XANES and Molecular Dynamics Simulations”, Journal of the American Chemical Society 132 (2010) 14901–14909
Della Longa S., Arcovito A., “X-rays induced lysis of the Fe-CO bond in carbonmonoxy-myoglobin”, Inorganic Chemistry 49 (2010) 9958–9961
Jacquamet L., Traoré D. A. K., Ferrer J.-L., Proux O., Testemale D., Hazemann J.-L., Nazarenko E., El Ghazouani A., Caux-Thang C., Duarte V., Latour J.-M., “Structural characterization of the active form of PerR: insights into the metal-induced activation of PerR and Fur proteins for DNA binding”, Mol. Microbiol. 73 (2009) 20-31
Arcovito A., Moschetti T., D’Angelo P., ManciniG., Vallone B., Brunori M, Della Longa S., “An X-ray diffraction and X-ray absorption spectroscopy joint study of neuroglobin”, Archives of Biochemistry and Biophysics 475 (2008) 7-13