30 - Zinc (Zn)
Zinc Datas in eV | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
EK | ΔEK | EL1 | ΔEL1 | EL2 | ΔEL2 | EL3 | ΔEL3 | EKα1 | ΔEKα1 | EKα2 | ΔEKα2 | EKß1 |
9659 | 1.67 | 1196.2 | 3.28 | 1044.9 | 0.72 | 1021.8 | 0.65 | 8638.86 | 2.32a / 3.40b | 8615.78 | 2.39a / 3.96b | 9572.0 |
Main beamline parameters at K-edge | |||||
---|---|---|---|---|---|
Bending Magnet | Monochromator | Mirrors | |||
Vertical div. (mrad) | Cristal type | Angle (°) | Resolution (eV) | Angle (mrad) | Cut-off energy (keV) |
0.181 | Si(220) | 19.55 | 0.495 | 4 | 14.5 |
Si(111) | 11.83 | 1.32 |
Main crystal analyzer spectrometer parameters at K-edge | |||
---|---|---|---|
Line | Crystal | ||
Name | E (eV) | Type | Bragg angle (°) |
EKα1 | 8638.86 | Si(642) | 81.425 |
Si(444) | 66.273 | ||
EKß1 | 9572.0 | Ge(555) | 82.509 |
Experiments already done with this element / available references
Earth & Environmental Sciences
Priadi P., Morin G., Ayrault S., Maillot F., Juillot F., Alliot I., Testemale D., Proux O., Brown Jr G.E., “EXAFS and SEM evidence for zinc sulphide solid phases in riverine suspended matter from the Seine River, France”, Environmental Science & Technology 46 (2012) 3712–3720
Legros S., Doelsch E., Masion A., Rose J., Borschneck D., Proux O., Hazemann J-L., Saint-Macary H., Bottero J-Y., “Combining size fractionation, scanning electron microscopy and X-ray absorption spectroscopy to probe Zn speciation in pig slurry”, Journal of Environmental Quality 39 (2010) 531-540
Vespa M., Lanson M., Manceau A., “Natural Attenuation of Zinc Pollution in Smelter‐Affected Soil”, Environmental Science & Technology 44 (2010) 7814–7820
Sarret G., Willems G., Isaure M.-P., Marcus M. A., Fakra S. C., Frérot H., Pairis S., Geoffroy N., Manceau A., Saumitou-Laprade P., “Zinc distribution and speciation in Arabidopsis halleri Arabidopsis lyrata progenies presenting various zinc accumulation capacities”, New Phytologist 184 (2009) 581-595
Diesing W.E., Sinaj S., Sarret G., Manceau A., Flura T., Demaria P., Siegenthaler A., Sappin-Didier V., Frossard E., “Zinc speciation and isotopic exchangeability in soils polluted with heavy metals”, European Journal of Soil Science, 59 (2008)716-729
Juillot F., Maréchal C., Ponthieu M., Cacaly S., Morin G., Benedetti M. Hazemann J.-L., Proux O., Guyot F., “Zn isotopic fractionation caused by sorption on goethite and 2-Lines ferrihydrite”, Geochimica Cosmochimica Acta 72 (2008) 4886–4900
Sammut M.L., Rose J., Fiani E., Depoux , Ziebel A., Hazemann J.-L, Proux O., Noack Y., “Determination of Zinc speciation in steel plant flying dust”, Chemosphere, 70 (2008) 1945–1951
Straczek A., Sarret G., Manceau A., Hinsinger P., Jaillard B., “Zinc distribution and speciation in roots of various genotypes of tobacco exposed to Zn”, Environ. Exp. Bot. 63 (2008) 80-90
Manceau A., Lanson M., Geoffroy N., “Natural speciation of Ni, Zn, Ba and As in ferromanganese coatings on quartz using X-ray fluorescence, absorption, and diffraction”, Geochimica et Cosmochimica Acta 71 (2007) 95-128
Guiné V., Spadini L., Sarret G., Muris M., Delolme C., Gaudet J.-P., Martins J. M. F., “Zinc Sorption to Three Gram-Negative Bacteria: Combined Titration, Modeling, and EXAFS Study”, Environmental Science & Technology 40 (2006) 1806-1813
Kirpichtchikova T., Manceau A., Spadini L., Panfili F., Marcus M., Jacquet T., “Speciation and solubility of heavy metals in contaminated soil using X-ray microfluorescence, EXAFS spectroscopy, chemical extraction, and thermodynamic modelling”, Geochimica et Cosmochimica Acta 70 (2006) 2163-2190
Schlegel M., Manceau A., “Evidence for the nucleation and epitaxial growth of Zn phyllosilicate on montmorillonite”, Geochimica et Cosmochimica Acta 70 (2006) 901-917
Isaure M.P., Manceau A., Geoffroy N., Laboudigue A., Tamura N., Marcus M.A., “Zinc mobility and speciation in soil covered by contaminated dredged sediment using micrometer-scale and bulk-averaging X-ray fluorescence, absorption and diffraction techniques”, Geochimica et Cosmochimica Acta 69 (2005) 1173-1198
Manceau A., Tommaseo C., Rihs S., Geoffroy N., Chateigner D., Schlegel M., Tisserand D., Marcus M.A., Tamura N., Chen Z.S. “Natural speciation of Mn, Ni and Zn at the micrometer scale in a clayey paddy soil using X-ray fluorescence, absorption, and diffraction”, Geochimica et Cosmochimica Acta 69 (2005) 4007-4034
Panfili F., Manceau A., Sarret G., Spadini L., Kirpichtchikova T., Bert V., Laboudigue A., Marcus M.A., Ahamdach N., Libert M.F., “The effect of phytostabilization on Zn speciation in a dredged contaminated sediment using scanning electron microscopy, X-ray fluorescence, EXAFS spectroscopy and principal components analysis”, Geochimica et Cosmochimica Acta 69 (2005) 2265-2284
Manceau A., Marcus M. A., Tamura N., Proux O., Geoffroy N., Lanson B., "Zn speciation in a soil of the Ohio River basin by combining x-ray fluorescence, absorption and diffraction at micrometer scales of resolution", Geochimica et Cosmochimica Acta 68 (2004) 2467-2483
Marcus M. A., Manceau A., Kersten M., "Mn, Fe, Zn and As speciation in a fast-growing ferromanganese marine nodule", Geochimica et Cosmochimica Acta 68 (2004) 3125-3136
Manceau A., Tamura N., Celestre R.S., MacDowell A.A., Geoffroy N., Sposito G., Padmore H.A., "Molecular-scale speciation of Zn and Ni in soil ferromanganese nodules from loess soils of the Mississippi basin", Environmental Science & Technology 37 (2003) 75-80
Isaure M.P., Laboudigue A., Manceau A., Sarret G., Tiffreau C., Trocellier P., Lamble G., Hazemann J.L., Chateigner D., "Quantitative Zn speciation in a contaminated dredged sediment by µPIXE, µSXRF, EXAFS spectroscopy and principal component analysis", Geochimica et Cosmochimica Acta 66 (2002) 1549-1567
Sarret G., P. Saumitou-Laprade, V. Bert, O. Proux, J.L. Hazemann, A. Traverse, M. Marcus, A. Manceau, "Forms of Zinc accumulated in hyperaccumulator Arabidopsis halleri", Plant Physiology 130 (2002) 1815-1826
Simonet V., Calzavara Y., Hazemann J.L., Argoud R., Geaymond O., Raoux D., "Structure of aqueous ZnBr2 solution probed by X-ray absorption in normal and hydrothermal conditions", Journal of Chemical Physics 116 (2002) 2997-3006
Simonet V., Calzavara Y., Hazemann J.L., Argoud R., Geaymond O., Raoux D., "X-ray absorption spectroscopy studies of ionic association in aqueous solutions of zinc bromide from normal to critical conditions", Journal of Chemical Physics 117 (2002) 2771-2781
Biology
Alies B., Sasaki I., Proux O., Sayen S., Guillon E., Faller P., Hureau C., “Zn impacts Cu coordination to amyloid-b, the Alzheimer’s peptide, but not the ROS production and the associated cell toxicity”, Chemical Communications 49 (2013) 1214-1216
Chevreux S., Llorens I., Solari P. L., Roudeau S., Devès G., Carmona A., Testemale D., Hazemann J.-L., Ortega R., “Coupling of Native IEF and Extended X-ray Absorption Fine Structure to Characterize Zinc Binding Sites from pI Isoforms of SOD1 and A4V Pathogenic Mutant”, Electrophoresis 33 (2012) 1276–1281
Giannozzi P., Jansen K., La Penna G., Minicozzi V., Morante S., Rossi G., Stellato F., “Zn induced structural aggregation patterns of β-amyloid peptides by first-principle simulations and XAS measurements”, Metallomics 4 (2012) 156-165
Alies B., Pradines V., Llorens-Alliot I., Sayen S., Guillon E., Hureau C., Faller P. “Zinc(II) modulates specifically amyloid formation and structure in model peptides”, J. of Biological Inorganic Chemistry 16 (2011) 333-340
Stellato F., Spevacek A., Proux O., Minicozzi V., Millhauser G., Morante S., “Zinc ions modulate the Cu coordination mode in Prion protein octa-repeat subdomains”, European Biophysics Journal40 (2011) 1259-1270