33 - Arsenic (As)
Arsenic Datas in eV | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
EK | ΔEK | EL1 | ΔEL1 | EL2 | ΔEL2 | EL3 | ΔEL3 | EKα1 | ΔEKα1 | EKα2 | ΔEKα2 | EKß1 |
11867 | 2.14 | 1527.0 | 3.79 | 1359.1 | 1.03 | 1323.6 | 0.94 | 10543.72 | 3.08 | 10507.99 | 3.17 | 11726.2 |
Main beamline parameters at K-edge | |||||
---|---|---|---|---|---|
Bending Magnet | Monochromator | Mirrors | |||
Vertical div. (mrad) | Cristal type | Angle (°) | Resolution (eV) | Angle (mrad) | Cut-off energy (keV) |
0.163 | Si(220) | 15.81 | 0.609 | 3.3 | 17.8 |
Si(111) | 9.60 | 1.62 |
Main crystal analyzer spectrometer parameters at K-edge | |||
---|---|---|---|
Line | Crystal | ||
Name | E (eV) | Type | Bragg angle (°) |
EKα1 | 10544 | Si(555) | 69.65 |
EKß1 | 11762 | Ge(844) | 66.29 |
Experiments already done with this element / available references
Earth & Environmental Sciences
Adra A., Morin G., Ona-Nguema G., Menguy N., Maillot F., Bruneel O., Casiot C., Lebrun S., Juillot F., Brest J., “Arsenic scavenging by Aluminum-substituted Ferrihydrites in a circumneutral pH river impacted by acid mine drainage”, Environmental Science and Technology, 47 (2013) 12784–12792
Couture R.-M., Rose J., Kumar N., Mitchell K., Wallschläger D., Van Cappellen P., “Sorption of Arsenite, Arsenate, and Thioarsenates to Iron Oxides and Iron Sulfides: A Kinetic and Spectroscopic Investigation”, Environmental Science and Technology (2013)
Couture R.-M., Wallschläger D., Rose J., Van Cappellen P., “Arsenic binding to organic and inorganic sulfur species during microbial sulfate reduction: a sediment flow-through reactor experiment”, Environmental Chemistry 10 (2013) 285-294
Maillot F., Morin G., Juillot F., Bruneel O., Casiot C., Ona-Nguema G., Wang Y., Lebrun S., Aubry E., Vlaic G., Brown G. E. Jr, “Structure and reactivity of As(III)- and As(V)-rich schwertmannites and amorphous ferric arsenate sulfate from the Carnoulès Acid Mine Drainage, France:Comparison with biotic and abiotic model compounds and implications for As remediation”, Geochimica et Cosmochimica Acta 104 (2013) 310-329
Qian Q., Brugger J., Testemale D., Skinner W., Pring A., “Formation of As(II)-pyrite during experimental replacement of magnetite under hydrothermal conditions”, Geochimica et Cosmochimica Acta 100 (2013) 1-10
Auffan M., Rose J., Proux O., Masion A., Liu W., Benameur L., Ziarelli F., Botta A., Chaneac C., Bottero J.-Y., “Magnetic nanoparticles and metalloid co-contamination of human dermal fibroblasts: is there a Trojan horse effect”, Environmental Science & Technology 46 (2012) 10789-10796
Volant A., Desoeuvre A., Casiot C., Lauga B., Delpoux S., Morin G., Personné J.C., Héry M., Elbaz-Poulichet F., Bertin P.N., Bruneel O., “Temporal variation in the arsenic-rich creek sediments of Carnoulès Mine, France”, Extremophiles 16 (2012) 645-657
Charlet L., Morin G., Rose J., Wang Y., Auffan M., Burnol A., Fernandez-Martinez A. “Reactivity at (nano)particle-water interfaces, redox processes, and arsenic transport in the environment”, Comptes Rendus Geoscience 343 (2011) 123-139
Testemale D., Pokrovski G.S., Hazemann J.-L., “Speciation of AsIII and AsV in hydrothermal fluids by in situ X-ray absorption spectroscopy”, European Journal of Mineralogy 23 (2011) 379-390
Borisova A.Y., Pokrovski G.S., Pichavant M., Freydier R., Candaudap F., “Arsenic enrichment in hydrous peraluminous melts: insights from femtosecond laser ablation – inductively coupled plasma – quadrupole mass spectrometry, and in situ X-ray absorption fine structure spectroscopy”, American Mineralogist 95 (2010) 1095-1104
James-Smith J., Cauzid J., Testemale D., Liu W., Hazemann J.-L., Proux O., Etschmann B., Philippot P., Banks D., Williams P., Brugger J., “Arsenic Speciation in fluid inclusions using X-ray Absorption Spectroscopy”, American Mineralogist 95 (2010) 921–932
Egal M., Casiot C., Morin G., Parmentier M., Bruneel O., Lebrun S., Elbaz-Poulichet F., “Kinetic control on the formation of tooeleite, schwertmannite and jarosite by Acidithiobacillus ferrooxidans strains in an As(III)-rich acid mine water”, Chemical Geology 265 (2009) 432-441
Fakih M., Davranche M., Dia A., Nowack B., Morin G., Petitjean P., Châtellier X., Gruau G., “Environmental impact of As(V)-Fe oxyhydroxide reductive dissolution: An experimental insight”, Chemical Geology 147 (2009) 83-95
Auffan M., Rose J., Proux O., Borschneck D., Masion A., Hazemann J.-L., Chaneac C., Jolivet J.-P., Wiesner M., Van Geen A., Bottero J.-Y., “Enhanced adsorption of arsenic onto nano-maghemites: As(III) as a probe of strong surface heterogeneity”, Langmuir 24 (2008) 3215-3222
Cancès B., Juillot F., Morin G., Laperche V., Polya D., Vaughan D.J., Hazemann J.-L., Proux O., Brown Jr. G. E., Calas G., “Changes in arsenic speciation through a contaminated soil profile: a XAS based study”, Science of the Total Environment 397 (2008) 178-189
Morin G., Ona-Nguema G., Wang Y., Menguy N., Juillot F., Proux O., Guyot F., Calas G., Brown Jr. G. E., “EXAFS analysis of arsenite and arsenate adsorption on maghemite”, Environmental Science & Technology 42 (2008) 2361-2366
Morin G., Calas G., "Arsenic in Soils, Mine Tailings, and Former Industrial Sites", Elements 2 (2006) 97-101
Cancès B., Juillot F., Morin G., Laperche V., Alvarez L., Proux O., Hazemann J-L., Brown Jr. G. E., Calas G., “XAS evidence of As(V) association with iron oxyhydroxides in a contaminated soil at a former arsenical insecticide processing plant”, Environmental Science & Technology 39 (2005) 9398-9405
Casiot C., Lebrun S., Morin G., Bruneel O., Personné J.C., Elbaz-Poulichet F., “Sorption and redox processes controlling arsenic fate and transport in a stream impacted by acid mine drainage”, Science of the Total Environment 347 (2005) 122-130
Ona-Nguema G., G. Morin, F. Guyot, O. Proux, J-L. Hazemann, M. Abdelmoula, G. Calas, "Biomineralogical processes controlling iron and arsenic mobility in anoxic systems", European Geosciences Union, 1st General Assembly, Nice (25 - 30 Avril 2004), Geophysical Research Abstracts 6 (2004) 07526
Testemale D., Hazemann J.-L., Pokrovski G., Roux J., Joly Y., "Study of the evolution of As(OH)3 arsenious acid structure in supercritical conditions: an EXAFS and XANES investigation", Journal of Chemical Physics 121 (2004) 8973-8982
Pokrovski G., I. Zakirov, J. Roux, D. Testemale, J.L. Hazemann, A. Bychkov, G. Golikova, "Experimental study of arsenic speciation in vapor phase to 500°C : Implications for As transport and fractionation in low-density crystal fluids and volcanic gases", Geochimica et Cosmochimica Acta 66 (2002) 3453-3480
Tournassat C., Charlet L., Bosbach D., Manceau A., "Arsenic(III) Oxidation by Birnessite and Precipitation of Manganese(II) Arsenate", Environmental Science & Technology 36 (2002) 493-500