24 - Chromium (Cr)
Chromium Datas in eV | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
EK | ΔEK | EL1 | ΔEL1 | EL2 | ΔEL2 | EL3 | ΔEL3 | EKα1 | ΔEKα1 | EKα2 | ΔEKα2 | EKß1 |
5989 | 1.08 | 696 | 2.54 | 583.8 | 0.29 | 574.1 | 0.27 | 5414.72 | 1.35a / 2.05b | 5405.51 | 1.37a / 2.64b | 5946.71 |
Main beamline parameters at K-edge | |||||
---|---|---|---|---|---|
Bending Magnet | Monochromator | Mirrors | |||
Vertical div. (mrad) | Cristal type | Angle (°) | Resolution (eV) | Angle (mrad) | Cut-off energy (keV) |
0.229 | Si(220) | 32.67 | 0.307 | 6.5 | 9.0 |
Si(111) | 19.30 | 0.819 |
Main crystal analyzer spectrometer parameters at K-edge | |||
---|---|---|---|
Line | Crystal | ||
Name | E (eV) | Type | Bragg angle (°) |
EKα1 | 5414.72 | Ge(422) | 82.485 |
Si(331) | 66.770 | ||
EKß1 | 5946.71 | Si(333) | 85.897 |
Experiments already done with this element / available references
Earth & Environmental Sciences
Juhin A., Morin G., Elkaim E., Frost D. J., Juillot F., Calas G., “Structure refinement of a synthetic knorringite, Mg3Cr2Si3O12”, American Mineralogist 95 (2010) 59-63
Villain O., Galoisy L., Calas G., “Spectroscopic and structural properties of Cr3+ in silicate glasses: Cr3+ does not probe the average glass structure”, Journal of Non-Crystalline Solids 356 (2010) 2228-2234
Juhin A., Calas G., Cabaret D., Galoisy L., Hazemann J-L., “Structural relaxation around substitutional Cr3+ in pyrope garnet”, American Mineralogist 93 (2008) 800-805
Juhin A., Calas G., Cabaret D., Galoisy L., Hazemann J.-L., “Structural relaxation around substitutional Cr3+ in MgAl2O4”, Physical Review B 76 (2007) 054105
Villain O., Calas G., Galoisy L., Cormier L., Hazemann J.-L., “XANES determination of chromium oxidation states in glasses: comparison with optical absorption spectroscopy”, Journal of the American Ceramic Society 90 (2007) 3578-3581
Chaurand P., Rose J., Briois V., Olivi L., Hazemann J.-L., Proux O., Domas J., Bottero J.-Y., “Environmental impacts of steel slag reused in road construction: a crystallographic and molecular (XANES) approach”, Journal of Hazardous Materials 139 (2007) 537–542
Chaurand Perrine, “Apport de la cristallochimie et de la spéciation du chrome et du vanadium à la modélisation de l’altération de granulats artificiels (sous-produits d’acierie)”, Thèse de l'Université Paul Cézanne (2006)
Doelsch, E., Basile-Doelsch I., Rose J., Masion A., Borschneck D., Hazemann J.-L., Saint Macary H., Bottero J.-Y., “New combination of EXAFS spectroscopy and density fractionation for the speciation of chromium within an andosol”, Environmental Science & Technology 40 (2006) 7602-7608
Material Science
Riglet-Martial Ch., Martin Ph., Testemale D., Sabathier-Devals C., Carlot G., Matheron P., Iltis X., Pasquet U., Valot C., Delafoy C., Largenton R., “Thermodynamics of chromium in UO2 fuel: a solubility model”, Journal of Nuclear Materials 447 (2014) 63–72
Ramos A. Y., Tolentino H. C. N., Soares M. M., Grenier S., Bunau O., Joly Y., Baudelet F., Wilhelm F., Rogalev A., Souza R. A., Souza-Neto N. M., Proux O., Testemale D., Caneiro A., “Emergence of ferromagnetism and Jahn-Teller distortion in LaMn1-xCrxO3 (x<0.15)”, Physical Review B (Rapid Communication - Editor's suggestion) 87 (2013) 220404
Maret M., Bley F., Meneghini C., Albrecht M., Köhler J., Bucher E., Hazemann J.-L., “The Cr local structure in epitaxial CrPt3(111) films probed using Polarized X-ray Absorption Fine Structure”, Journal of Physics: Condensed Matter 17 (2005) 2529–2541
Albrecht M., M. Maret, J. Köhler, B. Gilles, R. Poinsot, J.-L. Hazemann, J.-M. Tonnerre, C. Teodorescu, E. Bucher, "Structural and magnetic properties of Cr in Cr/Ru(0001) multilayers", Physical Review B 66 (2002) 205410
Chemistry, Catalysis & Electrochemistry
Ould-Chikh S., Proux O., Afanasiev P., Khrouz L., Hedhili M., Anjum D., Harb M., Geantet C., Basset J.-M., Puzenat E., “Photocatalysis with Chromium-Doped TiO2: Bulk and Surface Doping”, ChemSuschem 7 (2014) 1361–1371