29 - Copper (Cu)
Copper Datas in eV | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
EK | ΔEK | EL1 | ΔEL1 | EL2 | ΔEL2 | EL3 | ΔEL3 | EKα1 | ΔEKα1 | EKα2 | ΔEKα2 | EKß1 |
8979 | 1.55 | 1096.7 | 3.06 | 952.3 | 0.62 | 932.7 | 0.56 | 8047.78 | 2.11a / 3.20b | 8027.83 | 2.17a / 3.83b | 8905.29 |
Main beamline parameters at K-edge | |||||
---|---|---|---|---|---|
Bending Magnet | Monochromator | Mirrors | |||
Vertical div. (mrad) | Cristal type | Angle (°) | Resolution (eV) | Angle (mrad) | Cut-off energy (keV) |
0.187 | Si(220) | 21.10 | 0.460 | 4.3 | 13.5 |
Si(111) | 12.74 | 1.23 |
Main crystal analyzer spectrometer parameters at K-edge | |||
---|---|---|---|
Line | Crystal | ||
Name | E (eV) | Type | Bragg angle (°) |
EKα1 | 8047.78 | Si(444) | 79.330 |
EKß1 | 8905.29 |
Si(553) Si(642) Ge(800) |
79.930 73.584 79.86 |
Experiments already done with this element / available references
Earth & Environmental Sciences
Collin B., Doelsch E., Keller C., Cazevieille P., Tella M., Chaurand P., Panfili F., Hazeman J-L., Meunier J.-D. “Copper distribution and speciation in bamboo exposed to a high Cu concentration and Si supplementation. First evidence on the presence of reduced copper bound to sulfur compounds in Poaceae”, Environmental Pollution 187 (2014) 22-30
Manceau A., Simionovici A., Lanson M., Perrin J., Tucoulou R., Bohic S., Fakra S. C., Marcus M., Bedell J.P., Nagy K., “Thlaspi arvense binds Cu(II) as a bis-(L-histidinato) complex on root cell walls in an urban ecosystem”, Metallomics 5 (2013) 1674-1684
Schlegel M.L., Manceau A., “Binding mechanism of Cu(II) at the clay-water interface by powder and polarized EXAFS spectroscopy”, Geochimica et Cosmochimica Acta 113 (2013) 113-124
Pokrovsky O.S., Pokrovski G.S., Shirokova L.S., Gonzalez A.G., Emnova E.E., Feurtet-Mazel A., “Chemical and structural status of copper associated with oxygenic and anoxygenic phototrophs and heterotrophs: possible evolutionary consequences”, Geobiology 10 (2012) 130-149
Etschmann B., Liu W., Testemale D. Müller H., Proux O., Hazemann J.-L., Brugger J., “An in situ XAS study of copper transport in hydrothermal sulfuric solutions (25 °C to 600 °C, 600 to 180 bar): speciation and partitioning between vapor and liquid phases”, Geochimica et Cosmochimica Acta 74 (2010) 4723-4739
Manceau A., Matynia A., “The Nature of Cu Bonding to Natural Organic Matter”, Geochimica Cosmochimica Acta 74 (2010) 2556–2580
Liu W., Brugger J., Etschmann B., Testemale D., Hazemann J.-L., “The solubility of nantokite (CuCl(s)) and Cu speciation in low density fluids near the critical isochore: an in-situ XAS study”, Geochimica et Cosmochimica Acta 72 (2008) 4094–4106
Manceau A., Nagy K.L., Marcus M.A., Lanson M., Geoffroy N., Jacquet T., Kirpichtchikova T. “Formation of metallic copper nanoparticles at the soil-root interface”, Environmental Science & Technology 42 (2008) 1766-1772
Brugger J., Etschmann B., Liu W., Testemale D., Hazemann J.-L., Emerich H., van Beek W., Proux O., C. Tran, “An XAS study of the structure and thermodynamics of Cu(I) chloride complexes in brines up to high temperature (400°C, 600 bars)”, Geochimica et Cosmochimica Acta 71 (2007) 4920–4941
Chemistry, Catalysis & Electrochemistry
Soldo Y., E. Sibert, G. Tourillon, J.L. Hazemann, J.P. Levy, D. Aberdam, R. Faure, R. Durand, "In situ X-ray absorption spectroscopy study of copper under potential deposition on Pt(111): role of the anions on the Cu structural arrangement", Electrochimica Acta 47 (2002) 3081-3091
Biology
Jullien A.-S., Gateau C., Lebrun C., Kieffer I., Testemale D., Delangle P., “d-Penicillamine Tripodal Derivatives as Efficient Copper(I) Chelators”, Inorganic Chemistry 53 (2014) 5229-5239
Alies B., Sasaki I., Proux O., Sayen S., Guillon E., Faller P., Hureau C., “Zn impacts Cu coordination to amyloid-b, the Alzheimer’s peptide, but not the ROS production and the associated cell toxicity”, Chemical Communications 49 (2013) 1214-1216
Jullien A.-S., Gateau C., Kieffer I., Testemale D., Delangle P., “X-Ray Absorption Spectroscopy Proves the Trigonal Planar Sulfur-Only Coordination of Cu(I) with High Affinity Tripodal Pseudopeptides”, Inorganic Chemistry 52 (2013) 9954–9961
D'Angelo P., Della Longa S., Arcovito A., Mancini G., Zitolo A., Chillemi G., Giachin G., Legname G., Benetti F., “Effects of the pathological Q212P mutation on human prion protein non-octarepeat copper binding site”, Biochemistry 51 (2012) 6068–6079
Stellato F., Spevacek A., Proux O., Minicozzi V., Millhauser G., Morante S., “Zinc ions modulate the Cu coordination mode in Prion protein octa-repeat subdomains”, European Biophysics Journal40 (2011) 1259-1270
Benetti F., Ventura M., Salmini B., Ceola S., Carbonera D., Mammi S., Zitolo A., D’Angelo P., Urso E., Maffia M., Salvato B., Spisni E., "Cuprizone neurotoxicity, copper deficiency and neurodegeneration”, NeuroToxicology 31 (2010) 509–517
Petit-Hærtlein I., Girard E., Sarret G., Hazemann J.-L., Gourhant P., Kahn R., Coves J., “Evidence for conformational changes upon copper binding to Cupriavidus metallidurans CzcE”, Biochemistry 49 (2010) 1913–1922
Sarret G., Favier A., Covès J., Hazemann J.-L., Mergeay M., Bersch B. “CopK from Cupriavidus metallidurans CH34 Binds Cu(I) in a Tetrathioether Site: Characterization by X-ray Absorption and NMR Spectroscopy”, Journal of the American Chemical Society 132 (2010) 3770–3777
Poger D., Fillaux C., Miras R., Crouzy S., Delangle P., Mintz E., Den Auwer C., Ferrand M., “Interplay between glutathione, Atx1 and copper: X-ray absorption spectroscopy determination of Cu(I) environment in an Atx1 dimer”, Journal of Biological Inorganic Chemistry 13 (2008) 1239-1248
D’Angelo P., Pacello F., Mancini G., Proux O., Hazemann J.-L., Desideri A., Battistoni A., “X-ray absorption investigation of a unique protein domain able to bind both Cu(I) and Cu(II) at adjacent sites of the N-terminus of Haemophilus ducreyi Cu,Zn superoxide dismutase”, Biochemistry 44 (2005) 13144-13150